橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2001 Vol.24 No.3 P.188-190

橡胶技术网

稀土/高分子复合材料的射线屏蔽性能和磁性能

刘力  孙朝晖  吴友平 

摘 要:综述了稀土/高分子复合材料的射线屏蔽性能和磁性能。指出稀土/高分子复合材料在X射线屏蔽应用中可有效地弥补铅的弱吸收区,具有高稀土含量的复合高分子屏蔽材料具有强的热中子吸收能力,含稀土的共聚物具有强顺磁性。提出了制备磁性和磁智能稀土/高分子复合材料的可行性。
关键词:稀土;高分子;复合材料;射线屏蔽;磁性能;综述
分类号:TQ317 文献标识码:A

文章编号:1000-1255(2001)03-0188-03

Radiation shielding and magnetic properties of rare earth/polymer composites

Liu Li(College of Materials Science and Engineering, Beijing University of Chemical Technology,Beijing 100029, China) 
Sun Zhaohui(College of Materials Science and Engineering, Beijing University of Chemical Technology,Beijing 100029, China) 
Wu Youping(College of Materials Science and Engineering, Beijing University of Chemical Technology,Beijing 100029, China) 

AbstractThe radiation shielding and magnetic properties of rare earth/polymer composites were reviewed with 10 references. The rare earth/polymer composite could make up the feeble absorbing area in the application of X ray shield and could demonstrate strong hot neutron absorbing ability when the rare earth content was high enough. The composites also had strong paramagnetism.The feasibility of preparing magnetic and magnetic intelligence materials by rare earth/polymer composites Was proposed.
Keywords:rare earth;polymer;,composite;tadiatioin shielding;magnetic property;review

作者简介:刘力,男,30岁,硕士,讲师。已发表论文20余篇。
作者单位:刘力(北京化工大学材料科学与工程学院,北京100029) 
     孙朝晖(北京化工大学材料科学与工程学院,北京100029) 
     吴友平(北京化工大学材料科学与工程学院,北京100029) 

参考文献:

[1]Wolff N E, Pressley R J. Optical maser action in Eu3+ containing organic matrix[J]. Appl Phys Lett, 1963, 2(8): 152 ~ 154
[2]徐光宪.稀土[M].北京:冶金工业出版社,l995
[3]杨遇春.稀土漫谈[M].北京:化学工业出版社,1999
[4]Ueba Y, Banks E, Okamoto, et al. Investigation on the synthesis and characterizafion of rare earth metal containing polymers:Ⅱ. Fluorescence properties of Eu3 +-polymer complexes containingβ-diketone ligand[J]. J Appl Polym Sci, 1980, 25(12):2 007 ~ 2 017
[5]Acdachi G. Fluorescence of a Eu2+-(mathacryloyl -oxymethyl15 -crown- 5-oligoether) polymer complex[J]. Chem Express,1988, 3(2): 97 ~ 100
[6]Ida K. Resin composition containing rare earth element and production thereof[P]. Jpn Kokai Tokkyo Koho, JP 60 110 756 A2.1985
[7]Yoshioka N, Nishde H, Tsuchida E. Complexation of gadolinium ion with poly(methacrylic acid)s and magnetic properties of the complexes[D].Inorg Chem Acta, 1987,128(1): 135 ~ 138
[8]Cheng X S. Study on synthesis of tetraphenyl porphyrin metal polymer and its physicochemical proerties[D]. Osaka Faculty of Science, Osaka University, 1987
[9]姚康德.智能材料[M].天津:天津大学出版社,1995
[10]邱广明,杨春雁,孙宗华,等.单分散亚微米级磁性徽球的合成[J].功能高分子学报,1996,9(4):565~571

收稿日期:2000年11月6日

修稿日期:2000年12月20日

出版日期:2001年5月15日