橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2001 Vol.24 No.5 P.310-315

橡胶技术网

茂金属及非茂金属催化剂引发丁二烯聚合

Progress on metallocene and non-metallocene catalyst for 1, 3-butadiene polymerization

姜连升  张学全 

摘 要:综述了茂金属与非茂金属催化剂引发丁二烯聚合的研究进展.茂钒催化剂在丁二烯聚合中有较高的催化活性,聚合物顺-1,4-结构摩尔分数约为80%,1,2-结构摩尔分数约为20%.
关键词:茂金属催化剂;非茂金属催化剂;聚丁二烯;综述
分类号:TQ 314.24+2  文献标识码:A

文章编号:1000-1255(2001)05-0310-06

作者简介:姜连升,研究员.中国合成橡胶协会理事.已发表论文数十篇.
作者单位:姜连升(中国科学院长春应用化学研究所,吉林长春,130022) 
     张学全(中国科学院长春应用化学研究所,吉林长春,130022) 

参考文献:

[1]周秀中,王佰全,徐善生.均相烯烃聚合催化剂的进展[J].化学通报,1996(5):1~4
[2]Kaminsky W, Külper H, Brintzinger H H, et al. Polymerization of propene and butene with a chiral zirconocene and methylalumi noxane as cocatalyst[J] . Angrew Chem Int Ed Engl, 1985, 24:507
[3]孙会敏,江畹兰,白乃斌,等.茂金属催化剂及新型橡胶[J]橡胶工业,1998,45(1):37~44
[4]Kaminsky W, Schlobohm M. Makromol Chem Makromol Symp,1986, 4:103
[5]Ricci G, Panagia A, Porri L. Polymerization of 1, 3-dienes with catalysts based on mono-and bis-cyclopentadienyl derivatives of vanadium[J]. Polymer, 1996, 37(2): 363 ~ 365
[6]Oliva L, Longo P, Grassi A, et al. Polymerization of 1, 3-alkadi enes in the presence of Ni-and Ti-based catalystic systems containing methylaluminoxane[J]. Makromol Chem Rapid Com mum, 1990, 11:519 ~524
[7]Zambelli A, Pellecchia C, Oliva L, et al. Catalyst for syndio tactic-specific polymerization of styrene: Atentative interpreta tion of some experimental data[J]. Makromol Chem, 1991, 192:223 ~ 231
[8]Pellecchia C, Longo P, Proto A, et al. Novel aluminoxane-free catalysts for syndiotactic-spesific polymerization of styrene [J]. Makromol Chem Rapid Commum, 1992, 13:265 ~ 268
[9]Pduso A, Improta R, Zambelli A. Mechanism of isoprene and butadiene polymerization in the presence of CpTiCl3-MAO initiator: A theoretical study[J]. Macromolecules, 1997, 30(8):2219 ~ 2 227
[10]Ricci G, Italia S, Porri L. Polymerization of 1, 3-dienes with methylaluminoxane-triacetylacetonaeo vanadium [ J ] . Macromol Chem Phys, 1994, 195:1 389~ 1 397
[11]Ricci G, Italia S, Comitani C, et al. Polymerization of conjugated dialkenes with transition metal catalysts: Influence of methylalu minoxane on catalyst activity and stereospecificity[J]. Polymer Commum, 1991,32(17):514
[12]Lgai Shigeru, Lmaoka Koji, Kai Yoshiyuki, et al. Catalysts and manufacture of conjugated diene polymers using them[P]. Jpn Tokai Tokkyo Koho, JP 09 286 811. 1997
[13]Lkai Shigeru, Kai Yoshiyuki, Murakami Masato, et al. Vanadium metallocene compounds for polymerizarion of conjugated dienes [P]. Jpn Tokai Tokkyo Koho, JP 10 298 230. 1998
[14]Tsujimato Nobuhiro, Suzuki Michinori. Manufacture of conjugated diene polymers using metallocene catalysts[P]. Jpn Tokai Tokkyo Kobo, JP 09 316 122. 1997
[15]Tsujimoto Nobuhiro, Maeda Koji, Murakami Masato. Polymeriza tion catalyst process for the preparation of conjugated diene polymer in the presence thereof and polybutadiene thus prepared [P]. Eur Pat Appl, EP 0 919 574 A. 1998
[16]Maeda Kouji, Bandai Akira, Murakami Masato, et al. Preparation of conjugated diene polymers in the presense of metallocene polymerization catalysts[P]. Jpn Tokai Tokkyo Koho, JP 200 017 008. 2000
[17]Endo K, Uchida Y, Matsuda Y. Polymerizations of butadiene with Ni(acac) 2-methylaluminoxane catalysts[J]. Macromol Chem Phys, 1996,197:3515~3 521
[18]Tsujihon Nobuhiro, Akikawa Kazuhiro, Kotani Chikara. Nickel catalysts and manufacture of conjugated diene polymers with high cis-content narrow molecular weight distribution and low gel content[P]. Jpn Tokai Tokkyo Koho, JP 10 292 009. 1998
[19]Miyataka T, Kakugo M. Makromol Chem Mokromol Symp, 1993,66:203 ~ 208
[20]Kakugo Masakiro, Miyatake Tatsuya, Kawai Yoshio, et al. Catalyst for olefin polymerization and process for preparing olefin polymers [P]. PCT Int Appl, WO 8 702 370. 1987
[21]Schaverien C J, Van der Linden A, Orpen A G. Polymerization of α-olefins and dienes by sterically hinaered chelating alkoxide titanium and zirconium species[J]. Polymer Preprints, 1994, 35:672
[22]Van der Linden A, Schaverien C J, Meijboom N, et al. Polymer ization of α-olefins and butadiene and catalytic cyclotrmeriza tion of 1-alkyhes by a new class of group Ⅳ: catalysts. Controlof molocular weight and polymer microstructure via ligand tuningin sterically hindered chelating phenoxide titanium and zirconiumspecies[J]. J Am Chem Soc, 1995, 117:3 008 ~ 3 021
[23]Lido Porri, Giarrusso A, Ricci G, et al. Recent advances in the field of diolefin polymerization with transition metal catalysts [J]. Makromol Chem Makromol Symp, 1993, 66:231 ~ 244
[24]Wilson D J. Polymerization of 1, 3-butadiene using aluminox ane-based Nd-carboxylate catalysts [J]. Polymer International, 1996, 36:235 ~ 242
[25]Sone Takuo, Nonaka katsutoshi, Hattori lwakazu, et al. Method of producing conjugated diene polymers[P]. Eur Pat Appl, EP 0863 165 A. 1998
[26]Biagini Paolo, Lugli Gabriele, Garbassi Fabio, et al. Catalytic system and process for the production of polydiolefines[P]. Eu rPat Appl, EP 0 667 357 A. 1995

收稿日期:2000年10月13日

修稿日期:2001年4月16日

出版日期:2001年9月1日