橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2002 Vol.25 No.5 P.274-276

橡胶技术网

溶聚丁苯橡胶技术进展

Development technology of solution polymerization styrene buadiene rubber

孙健 

摘 要:从引发剂、偶联剂、改性及聚合工艺等诸方面介绍了2000年溶聚丁苯橡胶技术新进展,并对其在21世纪的发展方向进行了展望.
关键词:溶聚丁苯橡胶;引发剂;偶联剂;聚合工艺;技术进展;评述
分类号:TQ333.1  文献标识码:A

文章编号:1000-1255(2002)05-0274-03

作者简介:孙健,男,1968年出生,工程师.
作者单位:孙健(兰州化学工业公司,兰化工程公司,甘肃,兰州,730060) 

参考文献:

[1]Liu Qing, Zhang Chunqing, Yu Fengnian, et al. Preparation of multi - chelating organolithium initiator and its use in synthesizing diene polymer with wide molecular weight distribution and high Mooney viscosity[P]. 中国发明专利, CN 1 197 806. 1998
[2]Lee Kyong, Lee Bomjin. Solution polymerization for manufacture of styrene-butadiene rubber or butadiene rubber[P]. Jpn Kokai Tokkyo Koho, JP 248 014. 2000
[3]Halasa Adel Farhan, Hsu Wenliang, Zuppo J R. Calcium alkoxide- based catalysts system and preparation of high trans- low vinyl random SBR[P]. U S, US 990 670. 2000
[4]Halasa Adel Farham, Hsu Wenliang, Zuppo J R. Preparation of high - trans - SBR using calcium/lithium - based catalysts[P] .U S, US 2 342 096. 2000
[5]Kobayashi Naokazu, Tadaki Toshihiro, Akema Hiroshi. Polymodal conjugated diolefin vinyl aromate rubber composition[P]. Jpn Kokai Tokkyo Kobo, JP 1 000 970. 2000
[6]Oh Junghoon, Yu Dongsun, Yun Dongill. Preparation of butadiene or butadiene - styrene rubber containing pentaerythritol tetrachloride as coupling agent[P]. Repub Korea, KR 9 705 479. 1997
[7]Buzdugan Emil, Corceovei Mircea, Ghioca Paul Niculae, et al.Polymerization precess in solution using organolithium catalysts to obtain styrene - butadiene rubber[P]. Rom, RO 110 508. 1996
[8]Liu Qing, Fan Chi, Zhao Liyun. Manufacture of SSBR by solution polymerization[P].中国发明专利,CN 1 209 440.1999
[9]Quirk Roderic P, Lee Youngjoon, Zhou Jinping. Alkyllithiuminitiated copolymerization of styrene and butadiene: Alkali metal alkoxide effects[J]. Polym Prepr, 2000, 41 ( 1 ): 129 ~ 130
[10]Jungling Stephan, Schade Christian, Erbes Jorg. Producing rubber solution in vinylaromatic monomers by anionic polymerization in the presence of aromatic compds[J]. PCT Int Appl, WO 99 67 299. 1999
[11]Xue Hong, Wang Jun, He Jianjun, et al. Study on coupling reaction of butadiene -styrene solution polymerization system in the presence of diglyme[J]. Tanxingti, 1999, 9(1 ): 12 ~ 14
[12]Xie Qicheng, Huang Chuansheng, Lin Fu, et al. Specific SBR for tiretreads[P].中国发明专利,CN 1 222 529.1999
[13]Morita Koichi. Manufacture of diene polymers having modified end groups and rubber compositions based on them with improved dispersibility of fillers[P]. Jpn Kokai Tokkyo Koho, JP 349 632.1999


收稿日期:2002年6月10日

修稿日期:2002年6月20日

出版日期:2002年9月15日