橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2003 Vol.26 No.6 P.381-381

橡胶技术网

Atom transfer radical polymerization of butadiene initiated by PhCH2Cl/MoCl3(OC8H17)2/PPh3

Zhong LingCollege of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042,China) 
Jia BinbinCollege of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042,China) 
Hua JingCollege of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042,China) 
Xu LingCollege of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042,China) 
Chen DianbaoCollege of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042,China) 

Atom transfer radical polymerization of butadiene initiated by PhCH2Cl/MoCl3(OC8H17)2/PPh3

钟玲  贾彬彬  华静  徐玲  陈滇宝 

摘 要:用苄基氯/辛醇取代的MoCl3/三苯基膦引发体系引发丁二烯聚合,得到聚合物相对分子质量、转化率与聚合时间呈线性关系.结果表明,该催化体系可实现丁二烯的ATRP反应.
关键词:钼催化剂;丁二烯;原子转移自由基聚合
CLC Number:TQ33 Document ID:A

Foundation Item:Supported by National Natural Science Foundation of China (20074018).
Author Resume:Zhong Ling(1974-), postgraduate.Chen Dianbao,To whom all correspondences should be addressed.
     钟玲(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     贾彬彬(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     华静(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     徐玲(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 
     陈滇宝(青岛科技大学,高分子科学与工程学院,山东,青岛,266042) 

References:

[1]Randts J A M,Vande Geijin P, Van Faassen E E,et al. Organomet Chem, 1999,584: 246
[2]Francois S,Jerome C,Rinaldo. P C R Chimie, 2002,5:37
[3]Chen Dianbao, Fang Wangxi,Wang Lixia. Acta Polymerica Sinica, 1994,5:513


Manuscript Received:2003年7月30日

Published:2003年11月15日