橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2003 Vol.26 No.6 P.386-389

橡胶技术网

氯化聚乙烯与小分子化合物掺杂体

Research on organic hybrid of chlorinated polyethylene and small molecule

隋刚  梁吉  朱跃峰 

摘 要:介绍了氯化聚乙烯与多官能团小分子掺杂体的特殊性质及其机理.目前,该领域的研究重点在于对掺杂体形态结构和动态力学性能的分析与控制,应用这方面的研究成果可以开发出一系列具有优异阻尼性能、形状记忆效应以及其他独特功能的新材料.
关键词:氯化聚乙烯;有机杂化体;分子间氢键;动态力学性能;玻璃化转变;微观结构
分类号:TQ314.24  文献标识码:A

文章编号:1000-1255(2003)06-0386-04

作者简介:隋刚(1972-),博士后.已发表论文30余篇.
作者单位:隋刚(清华大学,机械工程系,北京,100084) 
     梁吉(清华大学,机械工程系,北京,100084) 
     朱跃峰(清华大学,机械工程系,北京,100084) 

参考文献:

[1]Ngai K L, Rendell R W. Antiplasticization effects on a secondary relaxation in plasticized glassy polycarbonates [ J ]. Macromolecules,1991, 24(1): 61 ~67
[2]Kalkar A K, Parkhi P S. Compatibility in polymer/plastizer blend system: Thermal, X - ray, and dynamic mechanical studies of PMMA/PTBF blends [J]. J Appl Polym Sci,1995,57(2): 233~243
[3]Smith P, Eisenberg A. Effect plasticization by amines on the physical properties of an acidic styrene copolymer [ J ]. J Polym Sci, Polym Phys,1988,26(3): 569~580
[4]Liu Y, Roy A K, Jones A A, et al. NMR study of plasticization and antiplasticization of a polymeric glass [J]. Macromolecules,1990,23(4): 968 ~977
[5]Xiao C, Wu J, Yang L, et al. Positronium annihilation lifetime and dynamic mechanical studies of γ - relaxation in BPA - PC and TMBPA- PC plasticized by TOP [J]. Macromolecules, 1999, 32(23) :7 913 ~7 920
[6]Brandys F A, Bazuin C G. Mixtures of an acid - functionalized mesogen with poly(4 - vinylpyridine) [J]. Chem Mater,1996,8( 1 ): 83 ~87
[7]Muthuhumar M, Ober C K, Thomas E L. Competing interactions and levels of ordering in self - organizing polymeric materials [ J ]. Science ,1997,277: 1 225 ~ 1 232
[8]Kato K, Kubota Y, Moteki T, et al. Doubly hydrogen -bonded liquid- crystalline complexes obtained by supramolecular selfassembly of 2,6 - diacylaminopyridines and 4 - alkoxybenzoic acids[J]. Chem Lett, 1995(12): 1 127~1 130
[9]Wu C, Yamagishi T, Nakamoto Y. Crystallization behaviour of hindered phenol on chlorinated polyethylene matrix [ J ]. Polymer International, 2001,50(10): 1 095 ~1 102
[10]Wu C, Mori K, Otani Y, et al. Effects of molecule aggregation state on dynamic mechanical properties of chlorinated polyethylene/hindered phenol blends [J]. Polymer, 2001, 42(17): 8 289 ~8 295
[11]Wu C, Otani Y, Namiki N, et al. Phase modification of acrylate rubber/ chlorinated polypropylene blends by a hindered phenol compound [J]. Polymer Journal, 2001,33(4): 322 ~329
[12]Wu C, Yamagishi T, Nakamoto Y, et al. Viscoelastic properties of an organic hybrid of chlorinated polyethylene and a small molecule [J]. J Polym Sci, Polym Phys, 2000, 38(5):1 341 ~1 347
[13]Wu C. Effects of a hindered phenol compound on the dynamic mechanic properties of chlorinated polyethylene, acrylic rubber, and their blend [J]. J Appl Polym Sci, 2001, 80(13): 2 468 ~2 473
[14]Nugay N, Erman B. Property optimization in nitrile rubber composites via hybrid filler systems [J]. J Appl Polym Sci, 2001, 79(2):366 ~ 374
[15]Wu C, Akiyama S, Mabuchi T, et al. Dynamic mechanic properties and morphologies of organic hybrids consisting of chlorinated polyethylene and hindered phenol [ J ]. Polymer Journal, 2001, 33 (10):792 ~ 799
[16]Wu C. Functional design of organic hybrids consisting of polarized polymers and hindered phenol [ J ]. J Mater Sci Lett, 2001,20(15):1 389 ~ 1 392
[17]Wu C, Otani Y, Namiki N, et al. Dynamic properties of an organic hybrid of chlorinated polyethylene and hindered phenol compound[J]. J Appl Polym Sci, 2001, 82(7): 1 788 ~1 793
[18]Payne A R. Hysteresis in rubber vulcanizates [ J ]. J Polym Sci,1974,18(48): 169 ~196
[19]Payne A R, Whittaker R E. Influence of hysteresis on tensile and fatigne failure in rubbers [J]. Rubber Chem Technol, 1972, 45(4):1 043 ~ 1 050
[20]Wang M J. Effect of polymer - filler and filler - filler interactions on dynamic properties of filled vulcanizates [J]. Rubber Chem Technol,1997,71(3): 520 ~590
[21]Wu C, Yarnagishi T, Nakamoto Y, et al. Organic hybrid of chlorinated polyethylene and hindered phenol(Ⅱ): Influence of the chemical structure of small molecules on viscoelastic properties [J]. J Polym Sci ,Polym Phys, 2000, 38(5): 1 496~1 503


收稿日期:2002年12月30日

修稿日期:2003年7月15日

出版日期:2003年11月15日