橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2004 Vol.27 No.1 P.56-59

橡胶技术网

羧酸型离聚体的研究进展

Research progress of carboxylate ionomers

刘大刚  谢洪泉 

摘 要:综述了羧酸型离聚体的合成、链结构和聚集体结构,和由其结构引起的特殊力学性能和溶液性质;介绍了羧酸型离聚体在共混物增容、包装材料及纳米复合材料等方面的应用及其发展.
关键词:羧酸型离聚体;合成;结构;性能;应用;综述
分类号:TQ333.99  文献标识码:A

文章编号:1000-1255(2004)01-0056-04

作者简介:刘大刚(1978-),男,硕士研究生.
作者单位:刘大刚(湖北省化学研究院,湖北,武汉,430074) 
     谢洪泉(华中科技大学,湖北,武汉,430074) 

参考文献:

[1]Eisenberg A , Nayratil M. Ion clustering viscoelastic relaxation in styrene - based ionomers[J]. Macromolecules 1974, 7 ( 1 ): 90 ~ 95
[2]Macknight W J, Lundberg R D. Elastomeric ionomers[J]. Rubber Chem Technol, 1984, 57 (3): 652 ~ 660
[3]敖枝平,谢洪泉.磺化丁苯橡胶离聚体与一些聚合物的熔融共混及产物性能[J].合成橡胶工业,1994,17(1):14~18
[4]Xie Hongquan, Xu Jigeng. Melt flow and mechanical properties of sulfonated butyl rubber ionomer[J]. Angew Makromol Chem,1990, 174:177
[5]汪雨明,谢洪泉.P(MMA-BA-AA-Na+)/PAn导电复合物的制备及其性能研究[J].高分子材料科学与工程,1996,12(1):125
[6]王洪祚,李字安,宋桂珍.不同合成方法对稀土离聚体荧光性质的影响[J].高分子材料科学与工程,1994,3(3):26
[7]Deporter C D, Venkateschanaran L N. Synthesis and characterization of well defined acrylic ion -containing di - and triblock copolymer[J]. Polymer Preprints, 1989, 30(1 ): 201 ~ 206
[8]谢洪泉.离子交联遥爪聚合物[J].弹性体,1994,4(3):37~4l
[9]向前,谢洪泉.端羧基聚丁二烯及端羧基聚(丁二烯-co-丙烯腈)离聚体的合成及表征[J].高分子学报,1995,4:420
[10]Datta S, De S K. Ionic thermoplastic elastomer based on maleated EPDM rubber[J]. J Appl Polym Sci, 1996,61 (1): 177 ~ 182
[11]谢洪泉,邓继春.顺酐化SBS的钠离聚体与丙烯酰胺的接枝共聚物的增容性及乳化性[J].合成橡胶工业,2002,25(6):387~388
[12]周健华,席世平.聚乙烯接枝马来酸盐离聚体FTIR的研究[J].功能高分子学报,1997,10(2):265~270
[13]包永忠,潘祖仁.离聚体的聚集态结构模型[J].高分子通报,1996,4:221~225
[14]Eisenberg A, Hird B, Moore R B. A new multiplet cluster model for the morphology of random ionomers[J] . Macromolecules,1990, 23:4098~4114
[15]谭晓明,谢洪泉.聚丙烯离聚体的制备及其力学性能[J].华中理工大学学报,1997,25(10):71~75
[16]Kim J S, Hwa N Y, Jamg S S. Comparision of clustering in various acrylate ionomers[J]. Polymer, 2001, 42(13): 5567 ~ 5571
[17]Hara M, Jar P. Melt rheology of ethylene ionomers blended with a small - molecule acid[J]. Polym Commun 1987, 28(2): 52 ~ 56
[18]Vanhoome P, Register R A. Low - shear melt rheology of partially - neutralized ethylene - methacrylic acid ionomers[J].Macromolecules, 1996, 29 (2): 598 ~ 606
[19]李卓美,冯克,曾兆华.离聚体溶液[J].物理化学学报,1994,10(7):666
[20]孙东成.离聚体增容剂的研究进展[J].高分子材料科学与工程,2002,18(3):26
[21]Peiffer D G. Structure and properties of blends containing ethylene -methacrylate copolymers[J ]. J Polym Sci, Polym Phys Ed,1992, 30:1045 ~ 1053
[22]梁莉,席世平.聚乙烯接枝马来酸锌离聚体对PC/PS体系增容作用的研究[J].中国塑料,1998,12(2):37~42
[23]Kim Y K, Ha C S. Rheological properties, tensile properties and morphology of PP/EPDM/ionomer ternary blends[J]. J Appl Polym Sci, 1994,51(8): 1453 ~ 1458
[24]Crown Zellerbach Corporation. Flexible packaging films of high density polyethylene of forming easily openable heatseals[P] .U S, US 4 188 441. 1976
[25]Zhu J L, Zhou Y H. Effects of ionomer films on secondary alkaline zinc electrodes [ J ] . Journal of Power Sources, 1998, 73 (2):266 ~ 270
[26]Lee K H, Park J K, Kim W J, et al. Electrochemical characteristics of pan ionomer based polymer electrolytes[J]. Electrochemical Acta, 2000,45(8): 1301 ~ 1306
[27]Kim C H, Lee K H, Kim W S, et al. Ion conductivities and interfacial of the plasticized polymer electrolytes based on poly (methyl methacrylate - co - Li maleate) . Journal of Power Sources[J], 2001, 94(2): 163 ~ 168
[28]Yuan G X, Zhao Y. Side -chain liquid crystalline ionomers[J].Polymer, 1995, 36 (14): 2725 ~ 2732
[29]Li M, Zhang Y B, Jiang M, et al. Studies on novel surfactant free polystyrene nanopartiles formed in microphase inversion[J].Macromolecules, 1998, 31 (20): 6841 ~ 6845
[30]Pereira P N R, Inokoshi S, Tagami J. In vitro secondary caries inhibition around fluoride releasing materials[J]. Journal of Dentistry, 1998, 26(5): 505 ~ 510
[31]Artistic Glass Products Company. Method for preparing laminated safety glass[P]. Eur Pat Appl, EP 483 087. 1992
[32]Jochen A K. Development of ionomer memberanes for fuel cells [J]. Journal of Membrane Science, 2001, 185 (2): 3 ~ 27


收稿日期:2003年3月10日

修稿日期:2003年9月10日

出版日期:2004年1月15日