参考文献：

[1]王世敏,许祖勋,傅品.纳米材料制备技术[M].北京:化学工业出版社,2002.128～142
[2]朱静.纳米材料和器件[M].北京:清华大学出版社,2001.68～102
[3]张志焜,崔作林.纳米技术与纳米材料[M].北京:国防工业出版社,2000.51～74
[4]Schwab J J, Lichtenhan J D. Polyhedral oligomeric silsesquioxane(POSS) -based polymers [ J ]. Appl Orgmet Chem, 1998,12 ( 1 ):707 ～ 710
[5]江大志,李效冬.新一代高性能POSS-聚合物材料[J].材料导报,2001,15(5):56
[6]Bharadwaj R K, Berry R J, Farmar B L. Molecular dynamics simulation study of norbornene-POSS polymers [ J ]. Polym Preprints,2004,41 ( 1 ): 530
[7]Lin Tingting, He Chaobin, Xiao Yang. Theoretical studies of monosubstitued and higher phenyl-substitued octahydrosilsesquioxanes [J]. J Phys Chem (B): Page Est, 2000,44 (4) :3 210 ～3 215
[8]张亚峰,孙陆逸,刘安华,等.笼状六面体倍半硅氧烷衍生物制备聚合物纳米复合材料[J].化学世界,2001,11(3):98～102
[9]Schwab J J, Reinerth S W A, Lichtenhan J D, et al. POSSTM nanostrutured chemicals: Tore multifunctional polymer additives[J]. Polym Pre,2001,42(2): 48
[10]Pittan J C U, Li Guizhi, Ni Hanli. Hybrid inorganic/organic crosslinked resins containing polyhedral oligomeric silsesquioxane[ J ]. Macromol Symp,2003,196 (6) :301 ～ 325
[11]Haddad T S, Lee A, Phillips S H. Poly ( dimethylsiloxanes )modified with inorganic polyhedra [ J] . Polym Pre, 2001,42(1) :88
[12]Haddad T S, Lee A, Mather P T, et al. Thermosets modified with hybrid inorganic/organic polyhedra[J]. Polym Pre,2000,41(1) :584
[13]Huang Junchao, He Chaobin, Xiao Yang, et al. Polyimide/POSS nanocomposites: Interfacial interaction, thermal properties and mechanical properties [ J ]. Polym, 2003,44 ( 8 ): 4 491 ～4 499
[14]Kim Kyungmin, Keum Dongki, Chujo Yoshiki. Organic-inorganic polymer hybrids using polyoxazoline initiated by functionalized silsesquioxane [ J]. Macromole, 2003,36 ( 3 ) :867 ～ 875
[15]Krzysztof Matyjaszewski, Miller P J, Pyun J, et al. Synthesis and characterization of star polymers with varying arm number, length and composition from organic and hybrid inorganic/organic multifunctional initiator[J]. Macromole,1999,32(7) :6 526 ～6 535
[16]王旭,黄锐,濮阳楠.聚合物基纳米复合材料的研究进展[J].塑料,2000,29(4):25～31
[17]张力群,吴友平,王益庆,等.橡胶的纳米增强及纳米复合技术[J].合成橡胶工业,2003,23(2):71～77
[18]Pyun J, Miller P J, Kichelbick G. et al. Synthesis of organic/inorganic hybrid materials from polysiloxane precuresors using atom transfer radical polymerization [J] . Macromole, 2001,30 ( 3 ):2 275 ～ 2 279
[19]Wright M E, Schorzman D A, Feher F J, et al. Synthesis and thermal curing of aryl-ethynyl-terminated coPOSS imide oligomers: New inorganic/organic hybrid resins[J]. Chem Mater,2003,15 ( 1 ) :264 ～ 268
[20]Pyun J, Matyjasewski K, Wu Jian, et al. ABA triblock copolymer containing polyhedral oligomericl silsesquioxane pendant groups: Synthesis and unique properties [J] . Polym, 2003,44(5) :2 769 ～2 770
[21]Zheng Lei, Waddon A J, Farris R J, et al. X-ray characterization of polyethylene polyhedral oligomeric silsesquioxane copolymers[J]. Macromole ,2002,35(3 ) :2 375 ～2 379
[22]Fu Bingxing, Zhang Wenhua, Hsiao B S,et al. Synthesis and characterization of segmented polyurethanes containing polyhedral oligomeric silsesquioxane nanostructured molecules [ J ] . High Perform Polym,2000,12(3) :565 ～571
[23]Kim Kyungmin, Chujo Yoshiki. Liquid-crystalline organic-inorganic hybrid polymer with functionalized silsesquioxane [J]. J Polymer Sci(A) :Polym Chem,2002, 39( 11 ) :4 035 ～4 043
[24]Haddad T S, Mather P T, Hong G. et al. Hybrid inorganic/organic diblock copolymers nanostructure in polyhedral oligomeric silsesquioxane polynrbornenes [ J ]. Mat Res Soc Symp Pro,2000,34(4): 628
[25]Carroll J B, Waddaon A J, Nakade H. et al. " Plug and play"polymers thermal and X-ray characterization of noncovalently grafted polyhedral oligomeric silsesquioxane (POSS)-polystyrene nanocomposites [ J ]. Macromole,2003,36 ( 5 ) :6 289 ～ 6 291
[26]Abad M J, Barral L, Fasce D P, et al. Epoxy networks containing large mass fractions of A monofunctional polyhedral oligomeric silsesquioxane ( POSS ) [J] . Macromole 2003,35 ( 8 ):3 128 ～3 135
[27]Bhardwaj R K, Berry R J, Farmer B L. Molecular dynamics simulation study of norbornene-POSS polymers [ J ]. Polym, 2000,41(S) :7 209 ～7 221
[28]Murfee H J, Thoms T P S, Greaves J, et al. New metallodendrimers containing an octakis ( diphenylphosphin ) -functionalized silsesquioxane core and ruthenium (Ⅱ):Based chromophores[J]. Inorg Chem,2000,39 ( 11 ) :5 209 ～ 5 217
[29]Haddad T S, Lichtenhan J D. Hybrid organic-inorganic thermoplastics: Styryl-based polyhedral oligomeric silsesxquioxane polymers[J]. Macromolecules, 1996,29(9) :7 302 ～ 7 304
[30]Haddad T S,Viers B D,Phillips S H. Polyhedral oligomeric silsesquioxane ( POSS ) -styrene macromers [J] . J Inorg and Orgmet Polym, 2001,11 ( 3 ) :255 ～ 258
[31]Costa R O R, Vasconcelos W L. Organic/inorganic nanocomposites star polymers via atom transfer radical polymerization of methyl methacrylate using octafunctional silsesquioxane cores[J]. Macromole,2001,34(7 ) :5 398 ～ 5 407
[32]Pyun J, Matyjaszewske K. The synthesis of hybrid polymers using atom transfer radical polymerization and block copolymers from polyhedral oligomeric silsesquioxane monomers [ J ].Macromole ,2000,33 (2) :217 ～ 220
[33]Xu Hongyao, Kuo Shiao-wei, Huang Chin-feng, et al. Characterization of poly ( vingl-pyrrolidone-co-isobutylstyryl polyhedral oligomeric silsesquioxane) nanocomposites[ J]. J Appl Poly Sci,2004,91(9) :2 208 ～2 215
[34]Constable G S, Lesser A J, Counghlin E B. Morphological and mechanical evaluaion of hybrid organic-inorganic thermoset copolymers of dicycylopentadiene and mono-or tris(norbornenyl) -substituted polyhedral oligomeric silsesquioxane [ J ] . Macromole,2004,37(6) :1 276 ～1 282
[35]Leu Chyi-ming, Reddy G M, Wei Kung-hwa, et al. Synthesis and dielectric properties of polyimide-chain-end tethered polyhedral oligomeric silsesquoxane nanocomposites [ J ] . Chem Mater,2003,15 ( 3 ) :2 261 ～ 2 265
[36]Pellice S A, Pfasce D, Willians R J J. Properties of epoxy networks derived from the reaction of diglycidyl ether of bisphenol A with polyhedral oligomeric silsesquoxanes bearing OH- functionalised organic substituents[ J]. J Polymer Sci(B): Polym Phys,2003 41(7):1 451 ～ 1 461
[37]Zheng Lei, Kasi R M, Farris R J, et al. Synthesis and thermal properties of hybrid copolymers of syndiotactic polystyrene and polyhedral oligmeric silsesquoxane[ J]. J Polym Sci(A): Polym Chem ,2002,40 (7) :885 ～ 891
[38]Zheng Lei, Farris R J, Bryan E, et al. Novel polyolefin nanocomposites: Synthesis and characterization of metallcence-catalyzed polyolefin polyhedral oligomeric silsesquoxane copolymers[J]. Macromole ,2001,34 ( 1 ): 8 034 ～ 8 039
[39]Fu B X, Hsiao B S, White H, et al. Nanoscale reinforcement of polyhedral oligomeric silsesquoxane(POSS) in polyurethane elastomer[ J ]. Polymer Internatinal,2003,49 ( 2 ) :427 ～ 440
[40]Zhang Wenhua, Fu B X, Seo Y. et al. Effect of methyl methearylate/polyhedral oligomeric silsesquioxane random copolymers in compatibization of polystyrene and poly (methyl methacrylate)blends[J]. Macromole ,2002 ,35 (3) :8 029 ～8 038
[41]Uribe A R, Mather P T, Haddad T S, et al. Viscoelastic and morphological behavior of hybrid styryl-based polyhedral oligomeric silsesquioxane (POSS) copolymers [ J ]. J Polym Sci ( B ):Polym Phys,2001,36(5) :1 857 ～ 1 872
[42]Fu B X, Michael Y G, Hsiao B S, et al. Physical gelation in ethylene-propylene copolymer melts induced by polyhedral oligomeric silsesquioxane ( POSS ) molecules [ J ]. Polym, 2003,44(5) :1 499 ～1 506
[43]Blanske R L, Phillips S H, Chaffee K, et al. The preparation and properties of organic/inorganic hybrid materials by blending polyhedral oligosilsesquioxanes into organic polymer[J]. Polym Pre ,2000,41 ( 1 ): 585
[44]Xu Hongyao, Kuo Shiao-wei, Lee J S, et al. Preparations,thermal properties, and Tg increase mechanism of inorganic/organic hybrid polymers based on polyhedral oligomeric silsesquioxanes[J]. Macromole,2002,35 (3) :8 788 ～ 8 793
[45]Feher F J, Luche S, Schwab J J, et al. Hybrid materials from epoxid-substituted POSS frameworks [ J ] . Polymer Preprints,2000,41(1): 526
[46]Devaux E, Rochery M, Bourbigo S. Polyurethane/clay and polyurethane/POSS nanocomposites as flame retarded coating for polyeaster and cotton fabies[J]. Fire Mater,2002,26(2) :149 ～ 154
[47]Gao Feng, Cuibertson B M, Tong Yuhua, et al. Evaluation of multi-methacrylates copolymerized with methacryl-POSS for potential organic-inorganic hybrid dental restorative materials [ J ].Polym Preprints ,2000,41 ( 1 ) :580
[48]Nam K W, Chang M W, Sook B, et al. Development of the reinforced acrylic-based hybrid denture composite resin with vingloligosilsesquioxane (POSS) [ J ]. Korean Acad Prosthodont,2000,38(6) :671
[49]Xiao S, Nguyen M, Gong Xiong, et al. Stabilizatin of semiconducting polymers with silsesquioxane [ J ]. Adv Funct Mater,2003,13(1) :813 ～901
[50]Leu Chyi-ming, Chang Yao-te, Wei Kung-hwa. Polyimide-sidechain tethered polyhedral oligomeric silsesquioxane nanocomposites for low-dielectric film applications[J]. Chem Mater,2003,15(4) :3 721 ～3 727
[51]Leu Chyi-ming, Reddy G M, Wei Kung-hwa, et al. Synthesis and dielectrics of polyimide-chain-end tethered polyhedral oligomeric silsesquioxane nanocomposites[ J]. Chem Mater,2003,15(1) :2 261 ～2 265
[52]Jeon H G, Mather P T, Haddad T S. Shape memory and nanostructure in poly ( norbornyl-POSS ) copolymers [ J ]. Polym Int,2000,48( 1 ) :453 ～457
[53]Viers B D, Esker A, Farmer K. Polyhedral oligomeric silsesquioxane (POSS) surfactants [ J ]. Polym Preprints,2001,42 ( 2 ) :94
[54]Pyun J, Miller P J, Matyjaszewski K. Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization[J]. Polym Preprints,2000,41 (1): 536
[55]Deng Jianjun, Polidan J T, Httle J R, et al. Polyhedral oligomeric silsesquioxane: A new class of amphiphilies at the air/water interface [ J ] . J Am Chem Soc, 2002, 124 ( 6 ): 15 194 ～15 195