橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2009 Vol.32 No.1 P.77-81

橡胶技术网

弹性离聚体的研究进展

谢洪泉 

摘 要:总结及评述了近年来弹性离聚体的研究进展,包括羧基离聚体、磺化离聚体及遥爪离聚体等,介绍了最近用新方法合成的新型离聚体.
关键词:弹性离聚体;羧基离聚体;磺化离聚体;遥爪离聚体;综述
分类号:TQ333.1  文献标识码:A

文章编号:1000-1255(2009)01-0077-05

Progress in research of elastomeric ionomers

Xie Hongquan 

作者简介:谢洪泉(1931-),男,教授,本刊顾问.
作者单位:谢洪泉(华中科技大学化学系,湖北,武汉,430074) 

参考文献:

[1]Eisenberg A.A new multiplet-cluster model for the morphology of random ionomer[J].Macromolecules,1990,23 (18):4098-4012.
[2]MacKnight W J,Earnest T R.Structure and properties of ionomers[J].J Polym Sci:Macrumol Rev,1981,61 (1):41-57.
[3]Antony P,De S K.Ionic thermoplastic elastomers[J].J Macromol Sci:Polym Rev,2001,C 41 (1/2):41-77.
[4]刘大刚,谢洪泉.羧酸型离聚体的研究进展[J].合成橡胶工业,2004,27(1):56-59.
[5]Alzorriz I L.Ionic elastomers based on carboxylated nitrile rubber and magnesium oxide[J].J Appl Polym Sci,2007,103(5):1894-1899.
[6]Ibarra L,Alzorriz M.Ionic elastomers based on carboxylated nitrilc rubber and calcium oxide[J],J Appl Polym Sci,2003,87(3):805-813.
[7]Datta S,Den S K.Ionic thermoplastic elastomers based on malcated EPDM rubber[J].J Appl Polym Sci,1996,61(1):177-186.
[8]Makowski H S,Lundbery R D,Westerman J L,et al.Sulfonated EPDM elastomeric ionomer[J].Polym Prepr,1978,19 (2):292-293.
[9]Ma Buyong,Xie Hongquan.Properties of sulfonated EPDM ionomers obtained by sulfonation in the presence of phase transfer catalyst[J].J Macrumol Sci(B):Phys,1989,28(1):51-68.
[10]Siadat R,Lundberg R D,Lenz R W.Preparation of an ionomer elastomer by continuous sulfonation in an extruder and neutralization in static mixers[J].Polym Eng Sci,1980,20:530-539.
[11]Makowski H S,Lndberg R D.Plasticization of neutralized sulfonated elastomeric ionomer[J].Polym Prepr,1978,19(2):304-305.
[12]马步勇,谢洪泉.磺化乙丙胶离聚体的熔融流动性及力学性能[J].弹性体,1999,9(2):6-9.
[13]Canter N H.Sulfonated butyl rubber ionomer:US,3642728[P].1972-02-15.
[14]Xu Jigeng,Xie Hongquan.Melt flow and mechanical properties of sulfonated butyl rubber ionomers[J].Angew Makromol Chem,1990,174:177-187.
[15]谢洪泉,徐际庚,胡慧贞.磺化丁基橡胶离聚体及其共混物的动态力学性能[J].高分子学报,1992(4):488-494.
[16]Weiss R A,Sen A,Wilkes C L,et al.Block copolymer ionomers (1):Synthesis and properties of sulfonated poly (styreneethylene/butylenes-styrene)[J].Polymer,1991,32 (10):1867-1874.
[17]Storey R F,Chiskolm B J,Lee Y K.Synthesis and mechanical properties of poly (styrene-isobutylene-styrene) block copolymet ionomers[J].Polym Eng Sci,1997,37(1):73-80.
[18]Ghosh S K,De P P,Khastgir D,et al.Physicochemical and dielectric properties of magnesium and barium ionomers based on sulfonated meleated SBS block eopolymer[J].J Appl Polym Sci,2000,77(4):816-825.
[19]Li Xiaodong,Xie Hongquan,Liu Xiangyao.Hydrogenation and neutralization of carboxylic styrene-butadiene latex to form thermoplastic elastomer with excellent thermooxidation resistance[J].J Appl Polym Sci,2002,83:1375-1384.
[20]Fitzgerald J J,Weiss R A.Synthesis,preparation and structure of sulfonated ionomer[J].J Macrumol Sci(C):Rev Macronol Chem Phys,1998,28(1):99-128.
[21]Samuel J,Xavier T,Kurian T.High styrene-rubber ionomer:An alternative to the thermoplastic elastomers[J].J Appl Polym Sci,2002,85:2294-2300.
[22]Ao Zhiping,Xie Hongquan,GuoJunshi.Melt flow and mechanical properties of sulfonated SBR ionomers and their polymer blends[J].J Macromol Sci (B):Phys,1995,34 (3):249-262.
[23]Xu Wenshu,Xie Hongquan,Ao Zhiping.Ionomers from sulfonated styrene-butadiene rubber without gel as a thermoplastic elastomer[J].Polym Mater Sci Eng,2005,92:488-489.
[24]徐文树,过俊石,谢洪泉,等.充油充填料的磺化SBR离聚体的性能[J].合成橡胶工业,1994,17(2):102-104.
[25]Liu Dagang,Xie Hongquan,Guan Jianguo.Preparation,characterization and some properties of ionomers from a sulfonated styrene-butadiene-styrene triblock copolymer without gelation[J].J Appl Polym Sci,2005,96:1398-1404.
[26]Weiss R A,Lundberg R D,Turner S R.Sulfonated polystyrene ionomer prepared by emulsion polymerization[J].J Polym Sci:Polym Chem Ed,1985,23:525-533.
[27]Siodat B,Oster B,Lenz R W.Preparation of ion-containing elastomers by emulsion copolymer of dienes with olefinic sulfohie acid salts[J].J Appl Polym Sci,1981,26(3):1027-1037.
[28]Broze G,Jerome R,Teyssie P H.Halato-telechelic polymers(1):Gel formation and its dependence on the ionic content[J].Macromolecules,1981,14(1):224-232.
[29]Broze G,Jerome R,Teyssie P H.Halato-telechelic polymer (2):Glass transition temperature and viscoelastic behavior[J].Polym Bun,1981,4(4):241-247.
[30]向前,黄茁,戴蜀娟,等.端羧基聚丁二烯及端羧基聚(丁二烯-丙烯腈)离聚体的合成及表征[J].高分子学报,1995(4):416-420.
[31]Mohajir Y,Bagrodia S,Wilkes G L,et al.New polyisobutylene-based model elastomer ionomers(Ⅵ):The effect of neutralizing agent on mechanical properties[J].J Appl Polym Sci,1984,29(6):1943-1950.
[32]Bagrodia S,Wilkes G L,Kennedy J P.New polyisobutylenebased model elastomer ionomer (Ⅷ):Thermomechanical analysis[J].J Appl Polym Sci,1985,30(5):2179-2193.
[33]Omeiss J,Mucheleissen E,Moller M.On the synthesis and association of polymers with terminal sulfonate groups[J].Polym Prepr,1986,27(1):213-214.
[34]Xie Hongquan,Chen Yong,Yang Wei,et al.Synthesis and characterization of maleated ionomers viaring-opening reaction of epoxidized styrene-butadiene rubber with potassium hydrogen maleate and study of their behavior as compatibilizer[J].J Appl Polym Sci,2006,101(1):792-798.
[35]喻武钢.谢洪泉.环氧化SBS开环制顺酐化离聚体及其部分性能研究[J].弹性体,2006,16(3):32-36.
[36]喻武钢,谢洪泉,佘万能.顺丁烯二酸钾基SBS离聚体的力学性能及其应用[J].合成橡胶工业,2007,30(3):183-186.
[37]Xie Hongquan,Chen Yong,Yang Wei,et al.Synthesis of sulfonated rubber ionomers by the ring-opening reaction of epoxidized styrene-butadiene rubber,their characterization and their properties[J].J Appl Polym Sci,2006,101 (5):3090-3096.
[38]喻武钢,谢洪泉.环氧化SBS开环制磺化离聚体及其部分性能研究[J].弹性体,2006,16(4):25-29.
[39]喻武钢,谢洪泉,余万能.磺酸钠基SBS离聚体的力学性能及其应用[J].合成橡胶工业,2007,30(2):151-154.
[40]赵巍,谢洪泉.两亲性硫酸钾基(苯乙烯-丁二烯-苯乙烯)嵌段共聚物离聚体的合成、表征及其性能[J].合成橡胶工业,2008,31(3):179-182.
[41]赵巍,谢洪泉,余万能.硫酸盐基两亲SBS离聚体的形态结构、力学性能及其应用[J].弹性体,2007,17(6):37-40.
[42]Zhao Wei,Xie Hongquan.Preparation of novel phosphated ionomer via ring-opening reaction of epoxidized SBS and its properties[J].合成橡胶工业,2008,31 (5):395.
[43]赵巍,谢洪泉,刘良炎.磷酸盐基两亲SBS离聚体的结构、力学性能及其应用[J].合成橡胶工业,2008,31(5):381-384.
[44]Xie Hongquan,Chen Yong,Guan Jianguo,et al.Novel method for preparation of quaternary ammonium ionomer from epoxidized styrene-butadiene-styrene triblock copelymer and its use as compatibilizer for blending of styrene-butadiene-styrene and chlorosulfonated polyethylene[J].J Appl Polym Sci,2006,99:1975-1980.

收稿日期:2007年8月23日

修稿日期:2008年11月15日

出版日期:2009年1月15日

请看PDF全文