橡胶技术网

合成橡胶工业
CHINA SYNTHETIC RUBBER INDUSTRY
2010 Vol.33 No.2 P.158

橡胶技术网

钐配合物作防老剂的天然橡胶硫化胶的热氧老化性能

谢婵  贾志欣  罗远芳  贾德民 

摘 要:合成了一种新型稀土(钐)配合物,将其作为橡胶防老剂应用于天然橡胶硫化胶,对硫化胶在热氧老化过程中的力学性能和氧化诱导时间变化进行了初步研究.结果表明,钐配合物可以显著提高天然橡胶硫化胶的耐热氧老化性能,其防老化效果优于常用橡胶防老剂4010 NA.
关键词:钐配合物;天然橡胶;力学性能;氧化诱导时间;热氧老化性能

Thermal-oxidative aging properties of natural rubber vulcanizates with Sm(Ⅲ) complex as antioxidant

Xie Chan(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China)  Jia Zhixin(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China)  Luo Yuanfang(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China)  Jia Demin(College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China) 

  Oxidative aging of rubber is one of the most serious problems in rubber technology because the absorption of a small amount of oxygen causes a considerable change in physical and mechanical properties of rubber. There are several different approaches to inhibit the oxidation reaction, and the addition of antioxidants seems to be the most convenient way to retard oxidation. Many studies indicate that rare earth ions have strong antioxidant ability, and rare earth complexes show great scavenging effect for free radicals.……

基金项目:Supported by National High Technology Research and Development Program 0fChina(2009 AA 03 Z 338).
作者简介:Xie Chan, doctoral student.
作者单位:谢婵(华南理工大学,材料科学与工程学院,广东,广州510640) 
     贾志欣(华南理工大学,材料科学与工程学院,广东,广州510640) 
     罗远芳(华南理工大学,材料科学与工程学院,广东,广州510640) 
     贾德民(华南理工大学,材料科学与工程学院,广东,广州510640) 

收稿日期:2009年11月5日

出版日期:2010年3月15日

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