橡胶技术网

轮胎工业
TIRE INDUSTRY
2007 Vol.27 No.9 P.540-544

橡胶技术网

OMMT/BIIR纳米复合材料的结构与性能研究

梁玉蓉 

摘 要:采用熔体插层法制备有机蒙脱土(OMMT)/BIIR纳米复合材料.结果表明,OMMT/BIIR纳米复合材料是有序插层型纳米复合材料,在OMMT用量(0~15份)较小的情况下,其物理性能随着OMMT用量的增大明显提高;与BIIR胶料相比,其气密性优异.
关键词:BIIR;有机蒙脱土;纳米复合材料;熔体插层;气密性
分类号:TQ333.6;TQ330.38+3  文献标识码:B

文章编号:1006-8171(2007)09-0540-05

Structure and properties of OMMT/BIIR nanocomposites

LIANG Yu-rong 

作者简介:梁玉蓉(1971-),女,山西太原人,太原工业学院副教授,博士,主要从事高分子材料加工与改性研究.
作者单位:梁玉蓉(太原工业学院,材料工程系,山西,太原,030008) 

参考文献:

[1]Giannelis E.Polymer layered silicate nanocomposites[J].Advanced Materials,1996,8(1):29-35.
[2]Pluta M,Galeski A,Alexandre M,et al.Polylactide/mont-morillonite nanocomposites and microcomposites prepared by melt blending:structure and some physical properties[J].J.Appl.Polym.Sci.,2002,86(6):1 497-1 506.
[3]Usuki A,Tukigase A,Kato M.Preparation and properties of EPDM-clay hybrids[J].Polymer,2002,43(8):2 185-2 189.
[4]Giannelis E P.Polymer-layered silicate nanocomposites:synthesis,properties and applications[J].Applied Organometallic Chemistry,1998,12(10-11):675-680.
[5]Morgan A B,Jeffrey W G.Characterization of polymer-layered silicate (clay) nanocomposites by transmission electron microscopy and X-ray diffraction:a comparative study[J].J.Appl.Polym.Sci.,2003,87(8):1 329-1 338.
[6]Dietsche F,Mulhaupt R.Thermal properties and flammability of arylic nanocoposites based upon organophilic layered silicate[J].Polymer Bulletin,1999,43(4-5):395-402.
[7]Zilg C,Thomann R,Miilhaupt R.Polyurethane nanocompo-sites containing laminated anisotropic nanoparticles derived from organophilic layered silicates[J].Advanced Materials,1999,11(1):49-52.
[8]Ganter M,Gronski W,Reichert P,et al.Rubber nanocom-posites:morphology and mechanical properties of BR and SBR vulcanizates reinforced by organophilic layered silicates[J].Rubber Chemistry and Technology,2001,74(2):221-235.
[9]Ma J,Xu J,Ren J H,et al.A new approach to polymer/mont-morillonitenanocomposites[J].Polymer,2003,44(16):4 619-4 624.
[10]Kim J T,Oh T S,Lee D H.Morphology and rheological properties of nanocomposites based on nitrile rubber and organophilic layered silicates[J].Polym.Int.,2003,52(7):1 203-1 208.
[11]Varghese S,Karger-Kocsis J,Gatos K G.Melt compounded epoxidized natural rubber/layered silicate nanocomposites:structure-properties relationships[J].Polymer,2003,44(14):3 977-3 983.
[12]Zhang L Q,Wang Y Z,Wang Y Q,et al.Morphology and mechanical properties of clay/styrene-butadiene rubber nanocomposites[J].J.Appl.Polym.Sci.,2000,78(11):1 873-1 878.
[13]Wu Y P,Zhang L Q,Wang Y Q,et al.Structure of carboxy-lated acrylonitrile-butadiene rubber(CNBR)-clay nanocomposites by co-coagulating rubber latex and clay aqueous suspension[J].J.Appl.Polym.Sci.,2001,82(11):2 842-2 848.
[14]Wang Y Z,Zhang L Q,Tang C H,et al.Preparation and characterization of rubber-clay nanocomposites[J].J.Appl.Polym.Sci.,2000,78(11):1 879-1 883.
[15]Varghese S,Karger-Kocsis J.Natural rubber-based nanocomposites by latex compounding with layered silicates[J].Polymer,2003,44(17):4 921-4 927.
[16]Alexandre M,Dubois P.Polymer-layered silicate nanocomposites:preparation,properties and uses of a new class of materials[J].Materials Science and Engineering(R:Reports),2000,28(1-2):1-63.
[17]Elspass C W,Kresga E N,Peiffer D G,et al.Polymer nanocomposite formation by emulsion synthesis[P].WO 97/00 910.1997-01-09.
[18]Elspass C W,Peiffer D G,Kresga E N,et al.Nanocomposite materials (Law392)[P].USA:USP 5 883 173.1999-03-16.
[19]Elspass C W,Peiffer D G.Nanocomposite materials formed from inorganic layered materials dispersed in a polymer matrix[P].USA:USP 6 034 164.2000-03-07.
[20]Barrer R M.Diffusion of hydrocarbons in polyisobutylene[J].J.American Chem.Soc.,1951,73(9):4 072-4 075.
[21]Kojima Y,Fukumori K,Usuki A,et al.Gas permeabilities in rubber-clay hybrid[J].J.Mater.Sci.Lett.,1993,12(12):889-890.
[22]LeBaron P C,Wang Z,Pinnavaia T J.Polymer-layered silicate nanocomposites:an overview[J].Applied Clay Science,1999,15(1-2):11-29.
[23]韩秀山.丁基橡胶功能化品种[J].四川化工与腐蚀控制,2002(3):53-56.

出版日期:2007年9月10日

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