橡胶技术网

弹性体
CHINA ELASTOMERICS
2001 Vol.11 No.1 P.32-36

橡胶技术网

含聚双烯烃链节聚合物的加氢

柳庆春  张彬  朱家顺  陈滇宝

摘 要:介绍了目前用于含聚双烯烃链节的聚合物加氢的催化剂的种类,讨论了SBS加氢的机理及加氢动力学的研究进展。
关键词:加氢反应催化剂;含聚双烯烃链节的聚合物;加氢动力学
分类号:O63 文献标识码:B

文章编号:1005-3174(2001)01-0032-05

Hydrogenation of polymer containing polydiolefin units

LIU Qing-chunDepartment of Polymer Science and Engineering,Qingdao Institute of Chemical Technology,Qingdao 266042China) 
ZHANG BinDepartment of Polymer Science and Engineering,Qingdao Institute of Chemical Technology,Qingdao 266042China) 
ZHU Jia-shunDepartment of Polymer Science and Engineering,Qingdao Institute of Chemical Technology,Qingdao 266042China) 
CHEN Dian-baoDepartment of Polymer Science and Engineering,Qingdao Institute of Chemical Technology,Qingdao 266042China) 

AbstractThe catalysts used to hydrogenate polymer containing polydiolefin units are introduced in this paper.The mechanism of SBS hydrogenation and the development of the kinetics are also referred to.
Keywords
hydrogenation;catalysts;kinetics of hydrogenation

基金项目:国家自然科学基金资助项目(20074108)
作者简介:柳庆春(1979-),男,青岛化工学院高分子化学与物理专业硕士研究生。
作者单位:柳庆春(青岛化工学院高分子科学与工程系,山东青岛 266042) 
     张彬(青岛化工学院高分子科学与工程系,山东青岛 266042) 
     朱家顺(青岛化工学院高分子科学与工程系,山东青岛 266042) 
     陈滇宝(青岛化工学院高分子科学与工程系,山东青岛 266042) 

参考文献:

[1]Selectoively sulfonated block copolymers[P].USP 3 577 357,1971.
[2]Hydrogenated block copolymers of butadiene and a monovigyl aryl hydrocarbon[P].USP 3 431 323,1969.
[3]USP 3 333 024,1967.
[4]Partially hydrogenated block copolymers[P].USP 3 595 942,1971.
[5]Bolck copolymers having dissimilar nonelastomeric polymer blocks[P].USP 3 706 817,1972.
[6]Thermosplastic elastomeric materials[P].USP 3935 176,1976.
[7]杨京伟,鲍浪,徐瑞清.SBS新型加氢催化剂[J].合成橡胶工业,2000,23(1):31.
[8]杨京伟,鲍浪,徐瑞清等.SBS加氢动力学的研究[J].合成橡胶工业,2000,23(3):163.
[9]Hydrogenation catalyst[P].USP 3 855 185,1974.
[10]New catalyst for hydrogenation of elastomers and process of hydrogenation[P].USP 3 868 354,1975.
[11]Polycarbonate from carbonyl halide bischloroformate and dihydric phenol[P].USP 4501 875,1985.
[12]Olefin hydrogenation catalyst,process for hydrogenation polymers with the catelyst,and hydrogenated block copolymers produced by said processes[P].USP 4673 714,1987.
[13]茂金属催化剂用于丁苯嵌段共聚物加氢的研究[R].燕山石化99年度技术报告,1999.
[14]Singha H K,Sivaram S,Talwar S S.A New Method to Hydrogenate Nitrile Rubber in the Latex Form[J].Rubber Chem.Technol,1995,68:281.
[15]Mango L A,Lenz R W.Hydrogenation of Unsaturated Polymers with Diimide[J].Makromol Chem.,1973,163:13.
[16]Process for hydrogenation of carbon-carbon double bonds in an unsaturated polymer in latex form[P].USP 4 452 950,1984.
[17]Process for removal of catalyst residues[P].USP 3 793 306,1974.
[18]日本公开特许公报,昭57-202305,1982.
[19]Block polymer hydrogenation process[P].USP 3 644 588,1972.
[20]日本公开特许公报,昭58-17103,1983.
[21]Treatment of coupled polymers prior to by drogenation[P].USP 4 076 914,1978.
[22]Gillion L R.Macromolecules,1989,22:662.
[23]刘英,陈远荫,盛蓉生.富勒烯的金属配合物及其催化性能[J].分子催化,1997,11(5):394.
[24]Sloan M F,et al.J Amer Chem.Soc.,1963,(85):4011.
[25]刘峰,洪良构,应圣康,等.SBS加氢动力学研究[J].合成橡胶工业,1992,15(3):160.
[26]陈滇宝,仲崇祺,刘青,等.SBS常压加氢反应的红外光谱表征[J].合成橡胶工业,1999,22(4):216.
[27]陈滇宝,仲崇祺,唐学明,等.改型镍体系催化丁二烯顺1,4-聚合活性中心价态的研究[J].高分子学报,1990,(5):549.
[28]陈滇宝,仲崇祺,唐学明,等.丁二烯聚合镍催化剂的磁性[J].应用化学,1992,9(5):50.
[29]李晓东,过俊石,谢洪泉.氢化丁苯橡胶氢化度的测定[J].合成橡胶工业,2000,23(1):24.
[30]刘峰,洪良构,应圣康,等.SEBS热塑性弹性体的制备研究[J].合成橡胶工业,1992,15(1):28.
[31]董汝秀,张兴英,金关泰.用环烷酸钴-三异丁基铝-六甲基磷酸三酰胺催化加氢丁苯热塑性弹性体[J].合成橡胶工业,1992,15(5):274.
[32]董汝秀,张兴英,金关泰.SEBS的合成及其物理机械性能的研究[J].弹性体,1992,2(4):11.

收稿日期:2000年11月22日

出版日期:2001年2月1日

请看PDF全文